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变压吸附捕集CO2技术研究进展及其在石化行业应用案例分析

Research Progress of Pressure Swing Adsorption CO2 Capture Technology and Case Analysis of Its Application in Petrochemical Industry

  • 摘要:
      目的  作为CCUS(Carbon Capture, Utilization and Storage)中重要的碳捕集手段,变压吸附(Pressure Swing Adsorption,PSA)捕集CO2技术受到广泛应用。但过高的捕集能耗和运行成本制约了技术的推广和落地,如何精准地依据实际情况选择合适的捕集技术并降低捕集能耗尤为重要。
      方法  针对国内外变压吸附技术的基础研究与技术应用进行了讨论,并以某石化企业采用PSA技术捕集CO2的实际应用案例,分析了该技术在石化行业应用的经济性和前景。
      结果  在文章案例中,采用PSA吸附捕集CO2技术的项目对煤制氢装置净化单元、低温甲醇洗单元产出的约80万t中浓度碳源进行捕集封存,针对73.9%浓度的CO2原料气,装置实现了96%的CO2回收率以及98%的捕集纯度,在杂质气体方面,H2S、CH4及CH3OH均控制在0.015%以下,可实现约56 kWh/t CO2的捕集电耗。研究发现,变压吸附技术具备吸附剂再生能耗低、压阻低、工艺连续及吸附剂稳定性强的优势,表现出技术与经济可行性。由于变压吸附以物理吸附为主,因此PSA对于低浓度的原料气CO2处理可能会面临能耗较高且富集浓度不足的问题。
      结论  综上,PSA捕集CO2技术适宜用于中浓度碳源的处理,在未来石化、水泥等行业中排放的尾气处理上具有潜力。

     

    Abstract:
      Introduction  As an important carbon capture method in CCUS, pressure swing adsorption (PSA) CO2 capture technology has been widely used. However, the excessive capture energy consumption and operation cost restrict the promotion and implementation of the technology. How to accurately select the appropriate capture technology according to the actual situation and reduce the capture energy consumption is particularly important.
      Method  This paper discussed the basic research and technical application of PSA technology at home and abroad, and analyzed the economy and prospect of PSA technology in petrochemical industry based on a practical application case of PSA technology for CO2 capture in a petrochemical enterprise.
      Result  In this case, the project using PSA CO2 capture technology captured and stored about 800000 tons of medium-concentration carbon sources produced by the purification unit and low-temperature methanol washing unit of the coal-to-hydrogen plant. For 73.9% concentration of CO2 raw gas, the device achieved 96% CO2 recovery rate and 98% capture purity. H2S, CH4 and CH3OH are all controlled below 0.015%, which can achieve about 56 kWh/t CO2 capture power consumption. It is found that pressure swing adsorption technology has the advantages of low energy consumption, low piezoresistivity, continuous process and strong stability of adsorbent, which shows the technical and economic feasibility. Since pressure swing adsorption is mainly physical adsorption, PSA may face the problem of high energy consumption and insufficient enrichment concentration for the treatment of low concentration of CO2 feed gas.
      Conclusion  In summary, PSA CO2 capture technology is suitable for the treatment of medium concentration carbon sources, and has potential in thetreatment of exhaust emissions in petrochemical, cement and other industries in the future.

     

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